Budd P, Montgomery J, Evans J, Trickett M
Department of Archaeology, University of Durham, South Road, Durham DH1 3LE, UK.
Sci Total Environ. 2004 Jan 5;318(1-3):45-58. doi: 10.1016/S0048-9697(03)00357-7.
Lead concentration and isotope ratio data are presented for the tooth enamel of 77 individuals buried in England and spanning approximately 5000 years from the Neolithic until the 16th century AD. Whereas other tissues may be affected by diagenesis in the burial environment, the Pb concentration of tooth enamel is directly related to childhood exposure. This record is preserved post-mortem and over archaeological time. Tooth enamel Pb concentrations in the prehistoric period appear to be variable within the range 0.04 to approximately 0.4 ppm, with occasional higher levels. The Romano-British and medieval periods show a marked increase in Pb exposures with enamel concentrations reaching up to approximately 40 ppm. These exposures would today be associated with industrial pollution. Exposures appear to be highly variable compared with modern people, however, with many medieval individuals having very low enamel Pb concentrations comparable with prehistoric people. Lead isotope data refine this picture. We distinguish between the diverse isotopic ratios we believe to be characteristic of 'natural' exposure to Pb-from geological sources via the diet-and the much narrower isotopic range characteristic of exposure to technological Pb from ore sources. Taken together the data suggest that the maximum concentrations associated with 'non-technological' exposure at any period are approximately 0.5-1.0 ppm, similar to that reported for modern people in England.
本文呈现了77位埋葬在英格兰、跨越从新石器时代到公元16世纪约5000年时间的个体牙釉质中的铅浓度和同位素比值数据。虽然其他组织可能会受到埋葬环境中成岩作用的影响,但牙釉质中的铅浓度与儿童时期的暴露直接相关。这一记录在死后以及考古时间范围内得以保存。史前时期牙釉质中的铅浓度似乎在0.04至约0.4 ppm的范围内变化,偶尔会有更高的水平。罗马 - 不列颠和中世纪时期显示出铅暴露显著增加,牙釉质浓度高达约40 ppm。如今,这些暴露与工业污染相关。然而,与现代人相比,这些暴露似乎高度可变,许多中世纪个体的牙釉质铅浓度非常低,与史前人类相当。铅同位素数据细化了这一情况。我们区分了我们认为是通过饮食从地质来源“自然”接触铅所特有的不同同位素比值,以及来自矿石来源的技术铅接触所特有的更窄同位素范围。综合这些数据表明,任何时期与“非技术”暴露相关的最大浓度约为0.5 - 1.0 ppm,与英格兰现代人的报告值相似。