Dimitrov Ivaylo, Schlaad Helmut
Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Am Mühlenberg 1, 14476 Golm, Germany.
Chem Commun (Camb). 2003 Dec 7(23):2944-5. doi: 10.1039/b308990h.
Primary amine hydrochlorides promote a well-controlled ring-opening polymerisation of Z-L-lysine-N-carboxyanhydride in DMF at 40-80 degrees C; the polystyrene-poly(Z-L-lysine) block copolymers synthesised exhibit a very narrow molecular weight distribution, close to a Poisson distribution.
伯胺盐酸盐能在40-80摄氏度下促进Z-L-赖氨酸-N-羧基酐在N,N-二甲基甲酰胺中进行可控的开环聚合反应；合成得到的聚苯乙烯-聚（Z-L-赖氨酸）嵌段共聚物具有非常窄的分子量分布，接近泊松分布。
