Hue Bui T B, Dijkink Jan, Kuiper Sanne, Larson Kimberly K, Guziec Frank S, Goubitz Kees, Fraanje Jan, Schenk Henk, van Maarseveen Jan H, Hiemstra Henk
Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands.
Org Biomol Chem. 2003 Dec 21;1(24):4364-6. doi: 10.1039/b311415e. Epub 2003 Oct 29.
The compact tricyclic substructure of solanoeclepin A containing the cyclobutanone ring was prepared by using as the key step a highly regioselective intramolecular [2 + 2]-photocycloaddition reaction between one of the [small pi]-bonds of an allene and the CC double bond of a butenolide.
索拉诺穿心莲内酯A的紧密三环亚结构含有环丁酮环，其制备过程的关键步骤是在丙二烯的一个[小π]键与丁烯内酯的碳碳双键之间进行高度区域选择性的分子内[2 + 2]光环化加成反应。
