Malone Michael F, Huss Robert S, Doherty Michael F
Department of Chemical Engineering, University of Massachusetts, Amherst, Massachusetts 01003-9303, USA.
Environ Sci Technol. 2003 Dec 1;37(23):5325-9. doi: 10.1021/es034467w.
Reactive or catalytic distillation technology combines chemical synthesis steps with separations by distillation. This combination can lead to intensified, high-efficiency process systems with significant green engineering attributes. New applications and understanding have prompted growth in the use of reactive distillation for a variety of chemical syntheses, especially esterifications and etherifications involving oxygenated hydrocarbons. We describe several applications and the potential and tradeoffs for reactive distillation technology in the context of green engineering principles.
反应蒸馏技术将化学合成步骤与蒸馏分离相结合。这种结合可以产生具有显著绿色工程属性的强化高效工艺系统。新的应用和认识促使反应蒸馏在各种化学合成中的使用不断增加,特别是涉及含氧烃的酯化和醚化反应。我们根据绿色工程原理描述了反应蒸馏技术的几种应用以及其潜力和权衡。