Leaver Stewart A, Kilner Colin A, Halcrow Malcolm A
Department of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, England.
Acta Crystallogr C. 2004 Jan;60(Pt 1):m1-3. doi: 10.1107/s0108270103026064. Epub 2003 Dec 6.
The title compound, [Cu(2)(OH)(2)(C(14)H(17)N(3))(2)]Cl(2).6H(2)O, is a crystallographically centrosymmetric dimer of square-pyramidal Cu(II) centres, with a basal-basal Cu(2)(mu-OH)(2) bridging motif and apical pyridyl donors. The Cl(-) anion is hydrogen bonded to one O-H and one N-H group, and to three different water molecules. Because of disorder, the network of intramolecular hydrogen bonding in the hydrated lattice is only partly resolved.
标题化合物[Cu₂(OH)₂(C₁₄H₁₇N₃)₂]Cl₂·6H₂O是一种具有晶体学中心对称性的四方锥型Cu(II)中心二聚体，具有一个基底-基底[Cu₂(μ-OH)₂]²⁺桥连基序和顶端吡啶基供体。Cl⁻阴离子通过氢键与一个O-H和一个N-H基团以及三个不同的水分子相连。由于无序性，水合晶格中的分子内氢键网络仅部分解析。
