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Di-mu-hydroxo-bis[aqua(1,10-phen-anthroline-kappa2N,N')copper(II)] trans-bis(2-([(E)-5-formyl-2-oxido-kappaO-benzylidene]amino-kappaN)ethanesulfonato(2-))copper(II) hexahydrate.

作者信息

Jiang Yi-Min, Zeng Ju-Lan, Yu Kai-Bei

机构信息

College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China.

出版信息

Acta Crystallogr C. 2004 Oct;60(Pt 10):m543-5. doi: 10.1107/S0108270104021468. Epub 2004 Sep 25.

DOI:10.1107/S0108270104021468
PMID:15467135
Abstract

The title compound, [Cu(2)(OH)(2)(C(12)H(8)N(2))(2)(H(2)O)(2)][Cu(C(10)H(9)NO(5)S)(2)].6H(2)O, is comprised of a copper-centred complex cation and a copper-centred complex anion; the cation lies about an inversion centre and in the anion the Cu atom lies on an inversion centre. In the doubly charged bridged dicopper cation, each Cu centre has distorted square-pyramidal geometry. In the square-planar dianion, two sulfonate ligands are trans coordinated to the Cu atom via a deprotonated hydroxyl O atom and an imine N atom, forming two six-membered chelate rings. The structure is stabilized by an extensive hydrogen-bond system and aromatic-ring stacking interactions.

摘要

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