Davda Rupali R, Dumesic James A
University of Wisconsin, Madison, 1415 Engineering Drive, Madison, Wisconsin 53706, USA.
Chem Commun (Camb). 2004 Jan 7(1):36-7. doi: 10.1039/b310152e. Epub 2003 Nov 20.
Hydrogen can be produced from aqueous solutions containing 10 wt% glucose with high selectivities through the combined use of a hydrogenation reactor for conversion of glucose to sorbitol, followed by a reforming reactor for conversion of sorbitol to H(2) and CO(2) and then a gas-liquid separator for the removal of high-pressure H(2)-rich reformate gas, ready for use in a fuel cell.
通过联合使用一个用于将葡萄糖转化为山梨醇的氢化反应器、一个用于将山梨醇转化为氢气和二氧化碳的重整反应器,以及一个用于去除高压富氢重整产物气体(以供燃料电池使用)的气液分离器,可以从含有10重量%葡萄糖的水溶液中以高选择性生产氢气。