Edmondson Steve, Osborne Vicky L, Huck Wilhelm T S
Melville Laboratory for Polymer Synthesis, Department of Chemistry, Cambridge University, Lensfield Road, Cambridge, UKCB2 1EW.
Chem Soc Rev. 2004 Jan 10;33(1):14-22. doi: 10.1039/b210143m. Epub 2003 Dec 2.
Polymer brushes produced by controlled surface-initiated polymerization provide a route to surfaces coated with well-defined thin polymer films that are covalently bound to the substrate. All of the major controlled polymerization techniques have been applied to the synthesis of polymer brushes and examples of each are presented here. Many examples of brush synthesis in the literature have used the living atom transfer radical polymerization (ATRP) system, and in this tutorial review a particular focus is given to examples of this technique.
通过可控的表面引发聚合制备的聚合物刷为制备与基底共价键合的、具有明确结构的聚合物薄膜涂层表面提供了一条途径。所有主要的可控聚合技术都已应用于聚合物刷的合成，本文将给出每种技术的示例。文献中许多刷状聚合物合成的例子都使用了活性原子转移自由基聚合（ATRP）体系，在本综述中，将特别关注该技术的示例。
