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微孔金属有机材料:作为储氢吸附剂的有前途的候选材料。

Microporous metal organic materials: promising candidates as sorbents for hydrogen storage.

作者信息

Pan Long, Sander Michelle B, Huang Xiaoying, Li Jing, Smith Milton, Bittner Edward, Bockrath Bradley, Johnson J Karl

机构信息

Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, USA.

出版信息

J Am Chem Soc. 2004 Feb 11;126(5):1308-9. doi: 10.1021/ja0392871.

Abstract

Advancement in hydrogen storage techniques represents one of the most important areas of today's materials research. While extensive efforts have been made to the existing techniques, there is no viable storage technology capable of meeting the DOE cost and performance targets at the present time. New materials with significantly improved hydrogen adsorption capability are needed. Microporous metal coordination materials (MMOM) are promising candidates for use as sorbents in hydrogen adsorption. These materials possess physical characteristics similar to those of single-walled carbon nanotubes (SWNTs) but also exhibit a number of improved features. Here, we report a novel MMOM structure and its room-temperature hydrogen adsorption properties.

摘要

储氢技术的进步是当今材料研究最重要的领域之一。尽管人们对现有技术进行了广泛的研究,但目前还没有一种可行的存储技术能够满足美国能源部的成本和性能目标。需要具有显著提高的氢吸附能力的新材料。微孔金属配位材料(MMOM)有望用作氢吸附的吸附剂。这些材料具有与单壁碳纳米管(SWNT)相似的物理特性,但也表现出许多改进的特性。在此,我们报告了一种新型MMOM结构及其室温氢吸附特性。

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