一种新型手性三联吡啶大环化合物作为对映选择性识别氨基酸衍生物的荧光传感器。
A novel chiral terpyridine macrocycle as a fluorescent sensor for enantioselective recognition of amino acid derivatives.
作者信息
Wong Wing-Leung, Huang Ka-Hung, Teng Pang-Fei, Lee Chi-Sing, Kwong Hoi-Lun
机构信息
Department of Biology and Chemistry, Open Laboratory of Chirotechnology, Institute of Molecular Technology for Drugs Discovery and Synthesis, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon Tong, Hong Kong SAR, China.
出版信息
Chem Commun (Camb). 2004 Feb 21(4):384-5. doi: 10.1039/b313960c. Epub 2004 Jan 19.
Terpyridine macrocycle 1 is shown to be a strong chelating agent for organic ammonium salts and also a useful chromophore in fluorescent sensing. It exhibits very good enantioselectivity (K(obs)(S)/K(obs)(R)= 3.8) in chiral discrimination of alpha-phenylglycine methyl ester hydrochloride (PhEtOMe).
联吡啶大环化合物1被证明是一种用于有机铵盐的强螯合剂，也是荧光传感中一种有用的发色团。在对α-苯甘氨酸甲酯盐酸盐（PhEtOMe）的手性识别中，它表现出非常好的对映选择性（K(obs)(S)/K(obs)(R)= 3.8）。
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