Poleschak Ingo, Kern Jean-Marc, Sauvage Jean-Pierre
Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Université Louis Pasteur, Faculté de Chimie, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
Chem Commun (Camb). 2004 Feb 21(4):474-6. doi: 10.1039/b315080a. Epub 2004 Jan 23.
A new bistable rotaxane, consisting of a 2,2'-bipyridine-containing thread and a ring incorporating both a bidentate chelate and a tridentate fragment, has been prepared; this complex undergoes an electrochemically driven pirouetting motion of the ring around the axis which takes place on the millisecond timescale, i.e. several orders of magnitude faster than the other copper-based machines previously described.
一种新型双稳态轮烷已被制备出来，它由含2,2'-联吡啶的线轴和一个同时包含双齿螯合物及三齿片段的环组成；该配合物会发生环围绕轴的电化学驱动旋转运动，此运动发生在毫秒时间尺度上，即比之前描述的其他铜基分子机器快几个数量级。
