Sauvage Jean-Pierre
Laboratoire de Chimie Organo-Minerale, UMR 7513 du CNRS, Institut Le Bel, Universite Louis Pasteur, 4 rue Blaise Pascal, 67000, Strasbourg Cedex, France.
Chem Commun (Camb). 2005 Mar 28(12):1507-10. doi: 10.1039/b500680p. Epub 2005 Feb 22.
Transition metal-containing catenanes and rotaxanes are ideally suited to build molecular machines and motors; in the present review article, three examples from our group are discussed which consist of (i) a fast-moving electrochemically-driven pirouetting machine, (ii) a linear rotaxane dimer whose behaviour is reminiscent of muscles, in the sense that it can be stretched or contracted and (iii) a light-driven machine consisting of a catenane constructed around a ruthenium(II) centre.
含过渡金属的索烃和轮烷非常适合构建分子机器和马达;在本综述文章中,将讨论我们团队的三个例子,它们分别是:(i)一种快速移动的电化学驱动的旋转机器;(ii)一种线性轮烷二聚体,其行为类似于肌肉,即它可以拉伸或收缩;(iii)一种由围绕钌(II)中心构建的索烃组成的光驱动机器。