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聚[[双(1H-苯并咪唑-κN3)镉(II)]-μ-水-μ-琥珀酸根-κ2O1:O4]

Poly[[bis(1H-benzimidazole-kappaN3)cadmium(II)]-mu-aqua-mu-succinato-kappa2O1:O4].

作者信息

Liu Bing-Xin, Xu Duan-Jun

机构信息

Department of Chemistry, Zhejiang University, People's Republic of China.

出版信息

Acta Crystallogr C. 2004 Feb;60(Pt 2):m39-41. doi: 10.1107/S0108270103027847. Epub 2004 Jan 10.

Abstract

The title compound, Cd(C(4)H(4)O(4))(C(7)H(6)N(2))(2)(H(2)O), is a three-dimensional polymeric complex. The Cd(II) atom is located on an inversion centre and assumes an elongated octahedral coordination geometry, with a long Cd-O distance of 2.5381 (5) A to the coordinated bridging water molecule. The succinate dianion, located on another inversion centre, bridges adjacent Cd atoms to form succinate-bridged polymeric chains. The coordinated water molecule is located on a twofold axis and links adjacent succinate-bridged chains to form a water-bridged polymeric chain.

摘要

标题化合物[Cd(C₄H₄O₄)(C₇H₆N₂)₂(H₂O)]ₙ是一种三维聚合物配合物。Cd(II)原子位于一个对称中心上,呈拉长的八面体配位几何构型,与配位桥连水分子的Cd - O长距离为2.5381(5) Å。琥珀酸二阴离子位于另一个对称中心上,桥连相邻的Cd原子形成琥珀酸桥连的聚合物链。配位水分子位于一个二重轴上,连接相邻的琥珀酸桥连链形成水桥连的聚合物链。

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