（2,2'-联吡啶-κ2N,N'）（1,1-环丁烷二羧酸根-κ2O,O'）钯（II）、（1,1-环丁烷二羧酸根-κ2O,O'）（1,10-菲咯啉-κ2N,N'）钯（II）一水合物和（1,1-环丁烷二羧酸根-κ2O,O'）（1,10-菲咯啉-κ2N,N'）钯（II）二水合物
(2,2'-Bipyridine-kappa2N,N')(1,1-cyclobutanedicarboxylato-kappa2O,O')palladium(II), (1,1-cyclobutanedicarboxylato-kappa2O,O')(1,10-phenanthroline-kappa2N,N')palladium(II) monohydrate and (1,1-cyclobutanedicarboxylato-kappa2O,O')(1,10-phenanthroline-kappa2N,N')palladium(II) dihydrate.
作者信息
Muranishi Yasunori, Okabe Nobuo
机构信息
Faculty of Pharmaceutical Sciences, Kinki University, Kowakae 3-4-1, Higashiosaka, Osaka 577-8502, Japan.
出版信息
Acta Crystallogr C. 2004 Feb;60(Pt 2):m47-50. doi: 10.1107/S0108270103028130. Epub 2004 Jan 10.
In the three title compounds, [Pd(C(6)H(6)O(4))(C(10)H(8)N(2))], (I), [Pd(C(6)H(6)O(4))(C(12)H(8)N(2))].H(2)O, (IIa), and [Pd(C(6)H(6)O(4))(C(12)H(8)N(2))].2H(2)O, (IIb), respectively, each Pd(II) atom has a similar distorted cis-planar four-coordination geometry, completed by two O atoms of a bidentate 1,1-cyclobutanedicarboxylate anion and two N atoms of either a 2,2'-bipyridine or a 1,10-phenanthroline ligand.
在三种标题化合物[Pd(C₆H₆O₄)(C₁₀H₈N₂)]（I）、[Pd(C₆H₆O₄)(C₁₂H₈N₂)]·H₂O（IIa）和[Pd(C₆H₆O₄)(C₁₂H₈N₂)]·2H₂O（IIb）中，每个钯（II）原子都具有相似的扭曲顺式平面四配位几何结构，由双齿1,1 - 环丁烷二羧酸根阴离子的两个氧原子以及2,2'-联吡啶或1,10 - 菲咯啉配体的两个氮原子配位而成。
Zotero 插件