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Bis(2,2'-bipyridine-kappa2N,N')(oxalato-kappa2O,O')cobalt(II) pentahydrate.

作者信息

Sestan Marijana, Giester Gerald, Perić Berislav

机构信息

Rudjer Bosković Institute, PO Box 180, HR-10002 Zagreb, Croatia.

出版信息

Acta Crystallogr C. 2004 Nov;60(Pt 11):m595-7. doi: 10.1107/S0108270104025181. Epub 2004 Oct 31.

DOI:10.1107/S0108270104025181
PMID:15528815
Abstract

The synthesis and crystal structure of the mononuclear title compound, [Co(C(2)O(4))(C(10)H(8)N(2))(2)].5H(2)O, is reported. The Co atom is six-coordinated by two O atoms of a bidentate oxalate group and by four N atoms of two bipyridine ligands. The neutral [Co(C(2)O(4))(C(10)H(8)N(2))(2)] entities are connected by pi-pi stacking interactions of the aromatic systems into a two-dimensional layer, interconnected through a ladder-like hydrogen-bonding pattern of solvate water molecules.

摘要

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