双（2,2'-联吡啶-κ2N,N'）（1,10-菲咯啉-κ2N,N'）钌（II）四氰基铂（II）酸盐
Bis(2,2'-bipyridine-kappa2N,N')(1,10-phenanthroline-kappa2N,N')ruthenium(II) tetracyanoplatinate(II).
作者信息
Sakai Ken, Miyabe Yoshinobu
机构信息
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162-8601, Japan.
出版信息
Acta Crystallogr C. 2004 Feb;60(Pt 2):m69-72. doi: 10.1107/S0108270103029500. Epub 2004 Jan 31.
In the title compound, [Ru(C(10)H(8)N(2))(2)(C(12)H(8)N(2))][Pt(CN)(4)], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the pi-pi stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and Pt(CN)(4) units. Two adjacent one-dimensional chains form further stacks based on the pi-pi stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) A.
在标题化合物[Ru(C₁₀H₈N₂)₂(C₁₂H₈N₂)][Pt(CN)₄]中，阳离子和阴离子沿a轴交替排列，形成一维网络。这种一维特征源于π-π堆积以及邻菲罗啉（1,10-菲咯啉）与[Pt(CN)₄]²⁻单元之间形成的静电相互作用。基于邻菲罗啉部分之间的π-π堆积相互作用，两条相邻的一维链进一步堆叠，其平面间距为3.50(1) Å。
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