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{μ-N,N'-双[2-(二甲基氨基)乙基]草酰胺基(2-)-κ(6)N,N',O:N'',N''',O}双[(2,2'-联吡啶-κ2N,N')铜(II)] 双(高氯酸盐)

{Mu-N,N'-bis[2-(dimethylamino)ethyl]oxamidato(2-)-kappa(6)N,N',O':N'',N''',O}bis[(2,2'-bipyridine-kappa2N,N')copper(II)] bis(perchlorate).

作者信息

Sun Wei, Li Yan-Tuan, Wu Zhi-Yong, Zhang Shu-Fang, Yin Zhi-Wei

机构信息

Marine Drug and Food Institute, Ocean University of China, 266003 Qingdao, People's Republic of China.

出版信息

Acta Crystallogr C. 2008 Mar;64(Pt 3):m108-10. doi: 10.1107/S0108270107067558. Epub 2008 Feb 9.

DOI:10.1107/S0108270107067558
PMID:18322318
Abstract

In the crystal structure of the title complex, Cu(2)(C(10)H(20)N(4)O(2))(C(10)H(8)N(2))(2)(2), the deprotonated dmaeoxd(2-) ligand {H(2)dmaeoxd is N,N'-bis[2-(dimethylamino)ethyl]oxamide} occupies an inversion centre at the mid-point of the central C-C bond and is thus in a trans conformation. The two Cu(II) atoms are located in slightly distorted square-based pyramidal environments. The binuclear units interact with each other via pi-pi interactions to form a one-dimensional chain extending in the c direction.

摘要

在标题配合物Cu₂(C₁₀H₂₀N₄O₂)(C₁₀H₈N₂)₂₂的晶体结构中，去质子化的dmaeoxd²⁻配体{H₂dmaeoxd为N,N'-双[2-(二甲氨基)乙基]草酰胺}位于中心C-C键中点的对称中心上，因此呈反式构象。两个Cu(II)原子位于略微扭曲的四方锥环境中。双核单元通过π-π相互作用相互作用，形成沿c方向延伸的一维链。

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