Ko Chi-Chiu, Wu Li-Xin, Wong Keith Man-Chung, Zhu Nianyong, Yam Vivian Wing-Wah
Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, P R China.
Chemistry. 2004 Feb 6;10(3):766-76. doi: 10.1002/chem.200305485.
A series of spirooxazine-containing 2,2'-bipyridine ligands and their rhenium(i) tricarbonyl complexes has been designed and synthesized, and their photophysical, photochromic and electrochemical properties have been studied. The X-ray crystal structures of two of the complexes have been determined. Detailed studies showed that the emission properties of the complexes could readily be switched through photochromic reactions.
设计并合成了一系列含螺恶嗪的2,2'-联吡啶配体及其铼（I）三羰基配合物，并研究了它们的光物理、光致变色和电化学性质。测定了其中两种配合物的X射线晶体结构。详细研究表明，配合物的发光性质可通过光致变色反应轻松切换。
