Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China.
Dalton Trans. 2010 Jul 28;39(28):6475-82. doi: 10.1039/b927167h. Epub 2010 Jun 15.
A series of pyridine- and bipyridine-containing leucotriarylmethane ligands has been successfully synthesised and incorporated into tricarbonyl rhenium(I) diimine complexes. The X-ray crystal structures of two of the complexes have also been determined. The photoreactivity, photophysical and electrochemical properties of these ligands and their rhenium complexes were investigated. The photo-ionisation of the leucotriarylmethanes in the free ligands and their metal complexes and the subsequent change in absorption properties were also studied. Additionally, the electrochemistry of these ligands and complexes were investigated.
一系列含吡啶和联吡啶的亮氨酸三芳基甲烷配体已成功合成，并整合到三羰基铼（I）二亚胺配合物中。两个配合物的 X 射线晶体结构也已确定。研究了这些配体及其铼配合物的光反应性、光物理和电化学性质。还研究了游离配体及其金属配合物中亮氨酸三芳基甲烷的光致离子化以及随后吸收性质的变化。此外，还研究了这些配体和配合物的电化学。
