使用离散钯-N-杂环卡宾（NHC）配合物和原位钯/咪唑盐方案对芳基氯化物的高温胺化反应的研究。
Studies on high-temperature amination reactions of aromatic chlorides using discrete palladium-N-heterocyclic carbene (NHC) complexes and in situ palladium/imidazolium salt protocols.
作者信息
McCarroll Andrew J, Sandham David A, Titcomb Lisa R, Lewis Alexandra K de K, Cloke F Geoffrey N, Davies Brian P, de Santana Alejandro Perez, Hiller Wolfgang, Caddick Stephen
机构信息
The Chemistry Laboratory, School of Chemistry, Physics and Environmental Sciences, University of Sussex, Falmer Brighton, UK.
出版信息
Mol Divers. 2003;7(2-4):115-23. doi: 10.1023/b:modi.0000006863.14423.da.
The palladium catalysed coupling of aryl chlorides and amines can be readily achieved with short reaction times when carried out at high temperatures under thermal or microwave conditions. These coupling protocols are successful using two co-ordinate palladium-N-heterocyclic carbene complexes, or imidazolium salt protocols.
在热条件或微波条件下于高温下进行时，钯催化的芳基氯与胺的偶联反应能够在较短的反应时间内轻松实现。使用二配位钯-N-杂环卡宾配合物或咪唑盐方案，这些偶联方案是成功的。
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