微波、负载试剂与平行合成：异腈与酯的合成
Microwaves, supported-reagents and parallel synthesis: isocyanide and ester synthesis.
作者信息
Crosignani Stefano, Launay Delphine, Linclau Bruno, Bradley Mark
机构信息
Combinatorial Centre of Excellence, Department of Chemistry, University of Southampton, Highfield, Southampton, UK.
出版信息
Mol Divers. 2003;7(2-4):203-10. doi: 10.1023/b:modi.0000006861.68818.3f.
Abstract
The benefits of microwave irradiation are described for a number of important reactions such as amid and ester formation and dehydration of formamide to the corresponding isonitriles. Not only were reaction times dramatically reduced but the transformations were less prone to side reactions and decomposition.
摘要
微波辐射的益处已在许多重要反应中得到描述，如酰胺和酯的形成以及甲酰胺脱水生成相应的异腈。不仅反应时间大幅缩短，而且转化过程更不易发生副反应和分解。
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