Iwamatsu Sho-ichi, Uozaki Takashi, Kobayashi Kaoru, Re Suyong, Nagase Shigeru, Murata Shizuaki
Graduate School of Environmental Studies, Nagoya University, Nagoya 464-8601, Japan.
J Am Chem Soc. 2004 Mar 10;126(9):2668-9. doi: 10.1021/ja038537a.
The sequential carbon-carbon bond cleaving reactions of the diketone derivative of C60 with o-phenylenediamine give a novel bowl-shaped fullerene bearing a 20-membered ring orifice. The product reversibly encapsulates a water molecule into the fullerene cage for the first time.
C60的二酮衍生物与邻苯二胺的顺序碳-碳键裂解反应生成了一种带有20元环孔的新型碗状富勒烯。该产物首次将水分子可逆地封装到富勒烯笼中。
