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A possibility of element specific detection in HPLC by means of MIP-AES coupled with hydraulic high pressure nebulization.

作者信息

Heltai G, Józsa T, Percsich K

机构信息

Department of Chemistry and Biochemistry, University of Agricultural Sciences, H-2103, Gödöllö, Páter K. u. l., Hungary.

出版信息

Anal Bioanal Chem. 1996 Jun;355(5-6):638-41. doi: 10.1007/s0021663550638.

DOI:10.1007/s0021663550638
PMID:15045330
Abstract

An interface for coupling hydraulic high pressure nebulization (HHPN) with microwave induced plasma (MIP) atomic emission spectrometry (AES) is described. An appropriate spray chamber and aerosol desolvation system has been constructed for matching the HHPN generated aerosol flow with the loading capacity of toroidal argon and cylindrical helium MIP sources. The system has been optimized for aqueous solutions. Nanogram amounts of metals and nonmetals could be detected by the HHPN-MIP-AES technique developed. The HHPN devices are directly compatible with HPLC solvent flow, therefore they can be directly coupled with HPLC separations in aqueous media.

摘要

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