Ivkovic Aleksandar, Matovic Radomir, Saicic Radomir N
Faculty of Chemistry, University of Belgrade, Studentski trg 16, P.O. Box 158, 11000 Belgrade, Serbia and Montenegro.
Org Lett. 2004 Apr 15;6(8):1221-4. doi: 10.1021/ol049875z.
The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a semiochemical of Periplaneta americana. [reaction: see text]
烯烃复分解反应与β-碎裂反应相结合，为合成(Z)-构型的中环环烯烃提供了一条有效途径。该方法的通用性通过对美洲大蠊的一种信息素——Periplanone C的全合成得到了证明。[反应：见正文]
