Kalinin Alexey V, Chauder Brian A, Rakhit Suman, Snieckus Victor
Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.
Org Lett. 2003 Sep 18;5(19):3519-21. doi: 10.1021/ol035398t.
[reaction: see text] Intramolecular Heck and ring-closing metathesis reactions on key intermediates 10 and 15, respectively, provide efficient entries into seco-C/D ring analogues of Ergot alkaloids 12 and 16, compounds of potential synthetic and biological interest.
[反应：见正文] 分别在关键中间体10和15上进行分子内Heck反应和关环复分解反应，为高效合成麦角生物碱12和16的开环C/D环类似物提供了途径，这些化合物具有潜在的合成和生物学研究价值。
