双（丙酮-κO）双（N，N'-二甲基乙二胺-κ(2)N，N'）高氯酸铜（II）
Bis(acetone-kappaO)bis(N,N'-dimethylethylenediamine-kappa(2)N,N')copper(II) diperchlorate.
作者信息
Akitsu Takashiro, Einaga Yasuaki
机构信息
Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.
出版信息
Acta Crystallogr C. 2004 Apr;60(Pt 4):m162-4. doi: 10.1107/S010827010400349X. Epub 2004 Mar 11.
The title compound, Cu(C(4)H(12)N(2))(2)(C(3)H(6)O)(2)(2), is the first structurally characterized Cu(II) complex having acetone as axial ligands. The complex adopts an elongated octahedral trans-[CuN(4)O(2)] coordination geometry, with the Cu atom having 222 site symmetry. The axial Cu-O(acetone) and in-plane Cu-N bond lengths are 2.507 (5) and 2.041 (3) A, respectively.
标题化合物Cu(C₄H₁₂N₂)₂(C₃H₆O)₂₂是首个结构表征的以丙酮为轴向配体的Cu(II)配合物。该配合物采用拉长的八面体反式-[CuN₄O₂]配位几何构型，Cu原子具有222点群对称性。轴向的Cu-O(丙酮)键长和平面内的Cu-N键长分别为2.507 (5) Å和2.041 (3) Å。
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