链状聚[[二氯锌（II）]-μ-1,3-二-4-吡啶基丙烷-κ(2)N:N']
Catena-poly[[dichlorozinc(II)]-micro-1,3-di-4-pyridylpropane-kappa(2)N:N'].
作者信息
Chen Yu Biao, Kang Yao, Qin Ye Yan, Li Zhao Ji, Cheng Jian Kai, Hu Rui Feng, Wen Yi Hang, Yao Yuan Gen
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
出版信息
Acta Crystallogr C. 2004 Apr;60(Pt 4):m168-9. doi: 10.1107/S0108270104003592. Epub 2004 Mar 11.
The title compound, ZnCl(2)(bpp) (where bpp is 1,3-di-4-pyridylpropane, C(13)H(14)N(2)), has been prepared by the hydrothermal reaction of ZnCl(2) and bpp at 433 K. The Zn, Cl and central propyl C atom lie on the mirrors of the P2(1)/m space group. The molecular structure shows a weave-like polymeric chain. Each Zn atom is coordinated by two N atoms and two Cl atoms in a distorted tetrahedral geometry, with the Zn-N distance being 2.055 (5) A and the Zn-Cl distances being 2.239 (3) and 2.247 (2) A.
标题化合物[ZnCl₂(bpp)]ₙ（其中bpp为1,3 - 二 - 4 - 吡啶基丙烷，C₁₃H₁₄N₂）通过在433 K下ZnCl₂与bpp的水热反应制备而成。Zn、Cl和中心丙基C原子位于P2(1)/m空间群的镜面上。分子结构呈现出类似编织的聚合物链。每个Zn原子由两个N原子和两个Cl原子以扭曲的四面体几何构型配位，Zn - N距离为2.055(5) Å，Zn - Cl距离分别为2.239(3) Å和2.247(2) Å。
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