Xu Wei, Lin Jian-Li
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 12;64(Pt 8):m1025. doi: 10.1107/S1600536808020862.
In the title compound, CoCl(2)(C(13)H(14)N(2)), 1,3-bis-(4-pyrid-yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis-ected through the central C atom in the chain by a second mirror plane. There are some π-π stacking inter-ations in the crystal structure, with inter-planar distances of 3.449 Å, which are responsible for the supra-molecular assembly.
在标题化合物[CoCl₂(C₁₃H₁₄N₂)]ₙ中，1,3-双（4-吡啶基）丙烷（bpp）配体连接四配位的钴原子，形成一条延伸的一维锯齿链。四面体配位多面体中的钴原子和两个氯原子都位于一个镜面上，而bbp配体被链中的中心碳原子所在的第二个镜面平分。晶体结构中存在一些π-π堆积相互作用，平面间距为3.449 Å，这对超分子组装起作用。
