首个具有碗烯体系的碗状稳定中性自由基：电子结构的合成与表征
The first bowl-shaped stable neutral radical with a corannulene system: synthesis and characterization of the electronic structure.
作者信息
Morita Yasushi, Nishida Shinsuke, Kobayashi Tadahiro, Fukui Kozo, Sato Kazunobu, Shiomi Daisuke, Takui Takeji, Nakasuji Kazuhiro
机构信息
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
出版信息
Org Lett. 2004 Apr 29;6(9):1397-400. doi: 10.1021/ol0497786.
PMID:15101751
Abstract
[structure: see text] A bowl-shaped neutral radical with a corannulene system has been designed and synthesized for the first time as a stable solid in air. An unequivocal characterization of the electronic properties of the radical shows that an appreciable amount of spin delocalization extends onto the corannulene unit's curved surface.
摘要
[结构：见正文] 首次设计并合成了一种具有碗烯体系的碗状中性自由基，使其能在空气中以稳定固体形式存在。对该自由基电子性质的确切表征表明，可观数量的自旋离域延伸到了碗烯单元的曲面上。
Zotero 插件