Lu Ru-Qiang, Zhou Yi-Nyu, Yan Xiao-Yun, Shi Ke, Zheng Yu-Qing, Luo Ming, Wang Xin-Chang, Pei Jian, Xia Haiping, Zoppi Laura, Baldridge Kim K, Siegel Jay S, Cao Xiao-Yu
State Key Laboratory of Physical Chemistry for Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.
Chem Commun (Camb). 2015 Jan 31;51(9):1681-4. doi: 10.1039/c4cc08451a.
For the first time, electron-rich thiophene units were fused into the skeleton of corannulene to extend π-surfaces and tune arrangement in single crystals. Two isomeric butterfly-like thiophene-fused dibenzo[a,g]corannulenes (3 and 5) were synthesized. Isomer 3 showed p-type transport properties, with a hole mobility of 0.06 cm(2) V(-1) s(-1).
首次将富电子的噻吩单元融合到碗烯骨架中，以扩展π表面并调节单晶中的排列。合成了两种异构体的蝶状噻吩稠合二苯并[a,g]碗烯（3和5）。异构体3表现出p型传输特性，空穴迁移率为0.06 cm² V⁻¹ s⁻¹。
