Isotopomer encapsulation in a cylindrical molecular capsule: a probe for understanding noncovalent isotope effects on a molecular level.
作者信息
Rechavi Dalit, Scarso Alessandro, Rebek Julius
机构信息
The Skaggs Institute for Chemical Biology and the Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
出版信息
J Am Chem Soc. 2004 Jun 30;126(25):7738-9. doi: 10.1021/ja048366p.
PMID:15212496
Abstract
Isotope effects for the encapsulation of deuterated versus nondeuterated guests are determined. This system involves the use of social isomers, and the origin of the isotope effect is localized to methyl groups interacting with aromatic rings.
摘要
Zotero 插件