环状碳酸酯合成的新方法。
Novel methodologies for the synthesis of cyclic carbonates.
作者信息
Yoshida Masahiro, Ihara Masataka
机构信息
Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Sendai, 980-8578, Japan.
出版信息
Chemistry. 2004 Jun 21;10(12):2887-93. doi: 10.1002/chem.200305583.
Cyclic carbonates are valuable compounds that have applications in a variety of chemical fields. Methodologies for the synthesis of cyclic carbonates are well investigated in recent years, and the most successful and popular procedure is the utilization of CO(2). This paper presents recent progress in the synthesis of cyclic carbonates by a CO(2)-fixation process, which involves novel palladium-catalyzed CO(2)-recycling reactions.
环状碳酸酯是有价值的化合物，在各种化学领域都有应用。近年来，环状碳酸酯的合成方法得到了充分研究，最成功且最常用的方法是利用二氧化碳（CO₂）。本文介绍了通过二氧化碳固定过程合成环状碳酸酯的最新进展，该过程涉及新型钯催化的二氧化碳循环反应。
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