钯催化通过碳酸炔丙酯与原位生成的有机锌化合物合成茚衍生物。
Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds.
作者信息
Guan Zheng-Hui, Ren Zhi-Hui, Zhao Lian-Biao, Liang Yong-Min
机构信息
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China.
出版信息
Org Biomol Chem. 2008 Mar 21;6(6):1040-5. doi: 10.1039/b719957k. Epub 2008 Feb 12.
DOI:10.1039/b719957k
PMID:18327329
Abstract
The palladium-catalyzed carboannulation and arylation reaction of propargylic carbonates with in situ generated organozinc compounds produced an important new class of indene derivatives. The reaction proceeded under mild conditions, and indene products were isolated in good to excellent yields.
摘要
钯催化的碳酸炔丙酯与原位生成的有机锌化合物的碳环化和芳基化反应产生了一类重要的新型茚衍生物。该反应在温和条件下进行，茚产物的分离产率良好至优异。
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