通过吡啶鎓-π相互作用实现螺旋稳定化。
Helix stabilization through pyridinium-pi interactions.
作者信息
Heemstra Jennifer M, Moore Jeffrey S
机构信息
Departments of Chemistry and Materials Science & Engineering, The University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA.
出版信息
Chem Commun (Camb). 2004 Jul 7(13):1480-1. doi: 10.1039/b405980h. Epub 2004 May 25.
DOI:10.1039/b405980h
PMID:15216340
Abstract
Intramolecular cation-pi interactions between a methyl pyridinium ion and a phenyl ring stabilize the folded structure of a phenyleneethynylene oligomer.
摘要
甲基吡啶鎓离子与苯环之间的分子内阳离子-π相互作用稳定了亚苯基乙炔低聚物的折叠结构。
Zotero 插件