分子内阳离子-π相互作用控制非受限（苯基烷基）吡啶的构象。
Intramolecular cation-pi interactions control the conformation of nonrestricted (phenylalkyl)pyridines.
作者信息
Richter Isabella, Minari Jusaku, Axe Philip, Lowe John P, James Tony D, Sakurai Kazuo, Bull Steven D, Fossey John S
机构信息
Department of Chemistry, The University of Bath, Bath, UK.
出版信息
Chem Commun (Camb). 2008 Mar 7(9):1082-4. doi: 10.1039/b716937j. Epub 2008 Jan 8.
DOI:10.1039/b716937j
PMID:18292897
Abstract
NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular pi-stacking.
摘要
核Overhauser效应光谱法（NOEsy）和荧光光谱法表明，构象灵活的（苯基烷基）吡啶转化为其相应的N-甲基吡啶碘化物会导致分子内π-堆积。
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