Singh Pawan P, Maier Dirk E, Cushman John H, Campanella Osvaldo H
Food Science and Toxicology, University of Idaho, Moscow, ID 83844, USA.
J Math Biol. 2004 Jul;49(1):20-34. doi: 10.1007/s00285-003-0250-6. Epub 2004 Jan 2.
The general fluid transport equation presented in Part-I of this paper is used for predicting moisture transport and viscoelastic stresses during sorption and drying of soybeans. Predicted drying curves were validated using experimental data obtained from literature (average absolute difference 6-13%). For drying temperatures used in the soybean processing industry (70-93 degrees C), smooth moisture profiles were obtained, which indicated Fickian (Darcian) transport. As the drying temperature approached the glass transition temperature (25 degrees C at 10% moisture content), the moisture profiles became sharper, which indicated non-Fickian (non-Darcian) transport. The viscoelastic stress profiles clearly exhibited the role of the force terms during imbibition and drying. Increase in drying temperature tends to decrease the stress relaxation function but reduction in moisture content during drying tends to increase it. The increase in stress due to the reduction in moisture content below 10% was not compensated by an increase in drying temperature. Drying of soybeans below 10% moisture content should be avoided in the industry because this will lead to thicker flakes that reduce the amount of oil recovery. During imbibition of soybeans, a high magnitude of stresses was obtained in the rubbery regions, which may cause critical regions prone to fissuring. The role of glass transition on stress development and critical region development was clearly observed during drying and imbibition of soybeans.
本文第一部分提出的通用流体传输方程用于预测大豆吸附和干燥过程中的水分传输及粘弹性应力。利用从文献中获取的实验数据对预测的干燥曲线进行了验证(平均绝对差异为6 - 13%)。对于大豆加工业中使用的干燥温度(70 - 93摄氏度),得到了平滑的水分分布曲线,这表明是菲克(达西)传输。当干燥温度接近玻璃化转变温度(水分含量为10%时为25摄氏度)时,水分分布曲线变得更陡,这表明是非菲克(非达西)传输。粘弹性应力分布曲线清楚地显示了力项在吸水和干燥过程中的作用。干燥温度升高往往会降低应力松弛函数,但干燥过程中水分含量的降低往往会使其增加。水分含量降至10%以下导致的应力增加并未因干燥温度的升高而得到补偿。工业上应避免将大豆干燥至水分含量低于10%,因为这会导致豆片变厚,从而降低出油量。在大豆吸水过程中,橡胶态区域会产生较大的应力,这可能导致易出现裂缝的关键区域。在大豆干燥和吸水过程中,清楚地观察到了玻璃化转变对应力发展和关键区域发展的作用。