Ruocco G, Sciortino F, Zamponi F, De Michele C, Scopigno T
Dipartimento di Fisica, Universita di Roma La Sapienza, P.le Aldo Moro 2, 00185 Roma, Italy.
J Chem Phys. 2004 Jun 8;120(22):10666-80. doi: 10.1063/1.1736628.
The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic fragility proposed in the last years and discuss their interrelations. At the same time we analyze some recently introduced models for the statistical properties of the potential energy landscape. Building on the Adam-Gibbs relation, which connects structural relaxation times to configurational entropy, we analyze the relation between statistical properties of the landscape and fragility. We call attention to the fact that the knowledge of number, energy depth, and shape of the basins of the potential energy landscape may not be sufficient for predicting fragility. Finally, we discuss two different possibilities for generating strong behavior.
脆弱性的概念为根据动力学和/或热力学量的温度依赖性对不同的过冷液体进行排序提供了一种可能性。在此,我们回顾一下近年来提出的动力学和热力学脆弱性的定义,并讨论它们之间的相互关系。同时,我们分析一些最近引入的关于势能景观统计特性的模型。基于将结构弛豫时间与构型熵联系起来的亚当 - 吉布斯关系,我们分析景观的统计特性与脆弱性之间的关系。我们提请注意这样一个事实,即仅了解势能景观盆地的数量、能量深度和形状可能不足以预测脆弱性。最后,我们讨论产生强行为的两种不同可能性。