Suppr超能文献

慢弛豫系统的局部准平衡描述

Local quasi-equilibrium description of slow relaxation systems.

作者信息

Santamaría-Holek I, Pérez-Madrid A, Rubí J M

机构信息

Department de Fisica Fonamental, Facultat de Fisica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.

出版信息

J Chem Phys. 2004 Feb 8;120(6):2818-23. doi: 10.1063/1.1640346.

Abstract

We present a dynamical description of slow relaxation processes based on the extension of Onsager's fluctuation theory to systems in local quasi-equilibrium. A non-Markovian Fokker-Planck equation for the conditional probability density is derived, and from it we obtain the relaxation equation for the moments. We show that the fluctuation-dissipation theorem can be formulated in terms of the temperature of the system at local quasi-equilibrium which is related to that of the bath by means of a scaling factor revealing lack of thermal equilibrium. Our theory may be applied to a wide variety of systems undergoing slow relaxation. We discuss in particular slow dynamics in glassy systems and Brownian motion in a granular gas.

摘要

我们基于将昂萨格涨落理论扩展到局部准平衡系统,给出了慢弛豫过程的动力学描述。推导了条件概率密度的非马尔可夫福克 - 普朗克方程,并由此得到矩的弛豫方程。我们表明,涨落 - 耗散定理可以根据局部准平衡系统的温度来表述,该温度通过一个揭示热平衡缺失的缩放因子与浴的温度相关。我们的理论可应用于经历慢弛豫的各种系统。我们特别讨论了玻璃态系统中的慢动力学以及颗粒气体中的布朗运动。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验