用于在温和条件下使二氧化碳与环氧化物交替共聚的高活性二元催化剂体系。 - Suppr

Suppr

超能文献

Highly active, binary catalyst systems for the alternating copolymerization of CO2 and epoxides under mild conditions.

作者信息

Lu Xiao-Bing, Wang Yi

机构信息

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116 012, P. R. China.

出版信息

Angew Chem Int Ed Engl. 2004 Jul 5;43(27):3574-7. doi: 10.1002/anie.200453998.

DOI:10.1002/anie.200453998

PMID:15293249

Abstract

摘要

相似文献

Highly active, binary catalyst systems for the alternating copolymerization of CO2 and epoxides under mild conditions.用于在温和条件下使二氧化碳与环氧化物交替共聚的高活性二元催化剂体系。

Angew Chem Int Ed Engl. 2004 Jul 5;43(27):3574-7. doi: 10.1002/anie.200453998.

Design of highly active binary catalyst systems for CO2/epoxide copolymerization: polymer selectivity, enantioselectivity, and stereochemistry control.用于二氧化碳/环氧化物共聚的高活性二元催化剂体系的设计：聚合物选择性、对映选择性和立体化学控制

J Am Chem Soc. 2006 Feb 8;128(5):1664-74. doi: 10.1021/ja056383o.

Mechanistic aspects of the copolymerization of CO2 with epoxides using a thermally stable single-site cobalt(III) catalyst.使用热稳定单中心钴（III）催化剂使二氧化碳与环氧化物共聚的机理研究

J Am Chem Soc. 2009 Aug 19;131(32):11509-18. doi: 10.1021/ja9033999.

(Tetramethyltetraazaannulene)chromium chloride: a highly active catalyst for the alternating copolymerization of epoxides and carbon dioxide.（四甲基四氮杂环壬烯）氯化铬：一种用于环氧化物与二氧化碳交替共聚的高活性催化剂。

Inorg Chem. 2007 Jul 9;46(14):5474-6. doi: 10.1021/ic7007842. Epub 2007 Jun 13.

Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts.使用分子内双核锌催化剂实现环氧环己烷与二氧化碳的共聚反应。

Chemistry. 2005 Jun 6;11(12):3668-78. doi: 10.1002/chem.200401159.

Copolymerization of CO2 and epoxides catalyzed by metal salen complexes.金属双水杨醛缩乙二胺配合物催化二氧化碳与环氧化合物的共聚反应。

Acc Chem Res. 2004 Nov;37(11):836-44. doi: 10.1021/ar030240u.

Cobalt catalysts for the alternating copolymerization of propylene oxide and carbon dioxide: combining high activity and selectivity.用于环氧丙烷与二氧化碳交替共聚的钴催化剂：兼具高活性和选择性

J Am Chem Soc. 2005 Aug 10;127(31):10869-78. doi: 10.1021/ja051744l.

Computational study-led organocatalyst design: a novel, highly active urea-based catalyst for addition reactions to epoxides.计算研究主导的有机催化剂设计：一种用于环氧化物加成反应的新型高活性脲基催化剂。

J Org Chem. 2008 Feb 1;73(3):948-56. doi: 10.1021/jo702154m. Epub 2008 Jan 4.

Enantioselective polymerization of epoxides: a highly active and selective catalyst for the preparation of stereoregular polyethers and enantiopure epoxides.环氧化物的对映选择性聚合：一种用于制备立构规整聚醚和对映体纯环氧化物的高活性和高选择性催化剂。

J Am Chem Soc. 2008 Dec 31;130(52):17658-9. doi: 10.1021/ja807709j.

Binding of 4-(N,N-dimethylamino)pyridine to Salen- and Salan-Cr(III) cations: a mechanistic understanding on the difference in their catalytic activity for CO2/epoxide copolymerization.4-(N,N-二甲基氨基)吡啶与Salen-和Salan-Cr(III)阳离子的结合：对它们催化二氧化碳/环氧化物共聚反应活性差异的机理理解。

Inorg Chem. 2009 Apr 6;48(7):2830-6. doi: 10.1021/ic802384x.

引用本文的文献

The Role of Ligand Exchange in Salen Cobalt Complexes in the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide.手性席夫碱钴配合物在环氧丙烷与二氧化碳交替共聚中配体交换作用的研究

Int J Mol Sci. 2024 Oct 11;25(20):10946. doi: 10.3390/ijms252010946.

Recent advances in enantioselective ring-opening polymerization and copolymerization.对映选择性开环聚合和共聚反应的最新进展

Commun Chem. 2023 Sep 29;6(1):202. doi: 10.1038/s42004-023-01007-z.

Ti(III) Catalysts for CO/Epoxide Copolymerization at Unusual Ambient Pressure Conditions.用于在异常常压条件下进行CO/环氧化物共聚反应的三价钛催化剂。

Inorg Chem. 2023 Sep 18;62(37):14873-14887. doi: 10.1021/acs.inorgchem.3c01249. Epub 2023 Aug 31.

Biodegradable polycarbonates from lignocellulose based 4-pentenoic acid and carbon dioxide.由木质纤维素基4-戊烯酸和二氧化碳制成的可生物降解聚碳酸酯。

Front Chem. 2023 May 4;11:1202735. doi: 10.3389/fchem.2023.1202735. eCollection 2023.

Copolymerization of Carbon Dioxide with 1,2-Butylene Oxide and Terpolymerization with Various Epoxides for Tailorable Properties.二氧化碳与1,2-环氧丁烷的共聚以及与各种环氧化物的三元共聚以实现可定制性能

Polymers (Basel). 2023 Feb 1;15(3):748. doi: 10.3390/polym15030748.

Insights into the Mechanism of Carbon Dioxide and Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I) Heterodinuclear Catalyst.利用Co(III)/K(I)异双核催化剂对二氧化碳与环氧丙烷开环共聚反应机理的深入研究

J Am Chem Soc. 2022 Oct 5;144(39):17929-17938. doi: 10.1021/jacs.2c06921. Epub 2022 Sep 21.

Heterocycle/Heteroallene Ring-Opening Copolymerization: Selective Catalysis Delivering Alternating Copolymers.杂环/杂联烯开环共聚：选择性催化合成交替共聚物

Angew Chem Int Ed Engl. 2022 Jan 3;61(1):e202104495. doi: 10.1002/anie.202104495. Epub 2021 Oct 19.

Reaction of phenylene(salicyalideneiminato)cobalt(III) and l-cysteine in mixed aqueous medium: kinetics and mechanism.亚水杨基苯胺基钴（III）与L-半胱氨酸在混合水介质中的反应：动力学与机理

Heliyon. 2020 Apr 30;6(4):e03850. doi: 10.1016/j.heliyon.2020.e03850. eCollection 2020 Apr.

Theoretical study on preference of open polymer vs. cyclic products in CO/epoxide copolymerization with cobalt(III)-salen bifunctional catalysts.钴（III）-salen双功能催化剂催化CO/环氧化物共聚中开环聚合物与环状产物偏好性的理论研究

J Mol Model. 2020 May 6;26(6):113. doi: 10.1007/s00894-020-04364-x.

Structure-Property Relationships of Poly(ethylene carbonate) and Poly(propylene carbonate).聚碳酸亚乙酯和聚碳酸亚丙酯的结构-性能关系

ACS Omega. 2017 Aug 22;2(8):4808-4819. doi: 10.1021/acsomega.7b00964. eCollection 2017 Aug 31.

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验