Shimakoshi Hisashi, Tokunaga Mami, Baba Tatsushi, Hisaeda Yoshio
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.
Chem Commun (Camb). 2004 Aug 21(16):1806-7. doi: 10.1039/b406400c. Epub 2004 Jul 28.
Dechlorination of 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) was catalyzed by a hydrophobic vitamin B(12), heptamethyl cobyrinate perchlorate, with a visible light irradiation system containing a [Ru(ii)(bpy)(3)]Cl(2) photosensitizer, and the hydrophobic vitamin B(12) showed high catalytic efficiency and stability during the reaction.
疏水性维生素B12，高氯酸七甲基钴胺素，在含有[Ru(ii)(bpy)(3)]Cl(2)光敏剂的可见光照射体系中催化1,1-双(4-氯苯基)-2,2,2-三氯乙烷（滴滴涕）的脱氯反应，且该疏水性维生素B12在反应过程中表现出高催化效率和稳定性。
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