聚合物负载的 B12 配合物与钌三吡啶敏化剂的光催化功能。
Photocatalytic function of a polymer-supported B12 complex with a ruthenium trisbipyridine photosensitizer.
机构信息
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan.
出版信息
Chem Commun (Camb). 2011 Jun 21;47(23):6548-50. doi: 10.1039/c1cc11970b. Epub 2011 May 9.
PMID:21552639
Abstract
The hybrid polymer was synthesized by a radical polymerization of a B(12) derivative and a Ru complex having styrene moieties in each peripheral position, and the hybrid polymer showed photocatalytic activity for molecular transformation with visible light irradiation.
摘要
该杂化聚合物是通过 B(12)衍生物和每个外围位置都具有苯乙烯部分的 Ru 配合物的自由基聚合合成的，该杂化聚合物在可见光照射下表现出光催化分子转化活性。
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