无外加光敏剂的 B12 配合物的光敏化催化。
Photosensitizing catalysis of the B12 complex without an additional photosensitizer.
机构信息
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Motooka, Fukuoka 819-0395, Japan.
出版信息
Chem Commun (Camb). 2011 Oct 21;47(39):10921-3. doi: 10.1039/c1cc12482j. Epub 2011 Jun 13.
PMID:21670798
Abstract
A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.
摘要
一种钴胺素衍生物，高氯酸七甲基钴叶立德，在三乙醇胺存在下经紫外光照射被激活形成 Co(I)物种，并用于脱氯反应，该光化学反应在离子液体中得到加速。
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