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平衡团簇相和低密度受阻无序态:短程吸引和长程排斥的作用。

Equilibrium cluster phases and low-density arrested disordered states: the role of short-range attraction and long-range repulsion.

作者信息

Sciortino Francesco, Mossa Stefano, Zaccarelli Emanuela, Tartaglia Piero

机构信息

Dipartimento di Fisica and INFM Udr and Center for Statistical Mechanics and Complexity, Università di Roma La Sapienza, Piazzale Aldo Moro 2, I-00185 Rome, Italy.

出版信息

Phys Rev Lett. 2004 Jul 30;93(5):055701. doi: 10.1103/PhysRevLett.93.055701. Epub 2004 Jul 29.

Abstract

We study a model in which particles interact with short-ranged attractive and long-ranged repulsive interactions, in an attempt to model the equilibrium cluster phase recently discovered in sterically stabilized colloidal systems in the presence of depletion interactions. At low packing fractions, particles form stable equilibrium clusters which act as building blocks of a cluster fluid. We study the possibility that cluster fluids generate a low-density disordered arrested phase, a gel, via a glass transition driven by the repulsive interaction. In this model the gel formation is formally described with the same physics of the glass formation.

摘要

我们研究了一个模型,其中粒子通过短程吸引和长程排斥相互作用进行相互作用,试图对最近在存在耗尽相互作用的空间稳定胶体系统中发现的平衡簇相进行建模。在低填充率下,粒子形成稳定的平衡簇,这些簇充当簇流体的构建块。我们研究了簇流体通过由排斥相互作用驱动的玻璃化转变产生低密度无序停滞相(一种凝胶)的可能性。在这个模型中,凝胶形成在形式上用与玻璃形成相同的物理原理来描述。

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