Camps M, Rigol A, Hillier S, Vidal M, Rauret G
Departament de Química Analítica-Universitat de Barcelona, Av. Diagonal 647, 3a Planta, 08028 Barcelona, Spain.
Sci Total Environ. 2004 Oct 1;332(1-3):23-38. doi: 10.1016/j.scitotenv.2004.04.008.
Agricultural practices (ploughing and reseeding, addition of lime and fertiliser) were tested as a feasible remediation strategy to reduce 137Cs (RCs) and 90Sr (RSr) soil-plant transfer in natural meadows in areas affected by the Chernobyl fallout. Field experiments were carried out for 2 years at six sites, covering dry and wet meadows. Observed results at field scale showed that ploughing plus reseeding provoked the main reduction in RSr transfer, with no further reduction after liming, while ploughing + reseeding + K fertiliser led to the maximum decrease in RCs transfer at most sites. The direct effects of agricultural practices on the exchange complex and soil solution composition were quantified by subsequent soil analyses. At the doses applied, lime did not affect the Ca + Mg concentrations in the exchange complex and soil solution of the ploughed soils, thus suggesting that the decrease in RSr transfer on treated plots was mainly due to the changes in the plant species after reseeding. With respect to RCs, changes in the K+NH4+ concentrations in the exchange complex and soil solution were consistent with changes in soil-plant transfer. Finally, RSr and RCs soil-plant transfer in ploughed plots was well predicted from soil properties, such as the solid-liquid distribution coefficient, the ionic composition of the soil solution and the exchangeable cations, with Pearson correlation coefficients of 0.98 and 0.86, respectively, between calculated and experimental log transfer factors.
在受切尔诺贝利核事故沉降影响的地区,人们对农业措施(深耕与重新播种、添加石灰和肥料)作为一种可行的修复策略进行了测试,以减少天然草地中¹³⁷Cs(铯-137)和⁹⁰Sr(锶-90)从土壤到植物的转移。在六个地点进行了为期两年的田间试验,涵盖了干草地和湿草地。田间尺度的观测结果表明,深耕加重新播种使锶-90的转移量大幅降低,添加石灰后没有进一步减少,而深耕 + 重新播种 + 钾肥在大多数地点使铯-137的转移量降至最低。通过后续的土壤分析对农业措施对交换复合体和土壤溶液成分的直接影响进行了量化。在所施用的剂量下,石灰并未影响深耕土壤交换复合体和土壤溶液中钙 + 镁的浓度,因此表明处理地块上锶-90转移量的减少主要是由于重新播种后植物种类的变化。对于铯-137,交换复合体和土壤溶液中钾⁺ + 铵⁺ 浓度的变化与土壤-植物转移的变化一致。最后,根据土壤性质,如固液分配系数、土壤溶液的离子组成和可交换阳离子,可以很好地预测深耕地块中锶-90和铯-137的土壤-植物转移情况,计算得到的和实验得到的对数转移因子之间的皮尔逊相关系数分别为0.98和0.86。