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在无钯和膦的情况下，碘化亚铜催化芳基卤化物与末端炔烃的偶联反应。

CuI-catalyzed coupling reaction of aryl halides with terminal alkynes in the absence of palladium and phosphine.

作者信息

Ma Dawei, Liu Feng

机构信息

Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.

出版信息

Chem Commun (Camb). 2004 Sep 7(17):1934-5. doi: 10.1039/b407090a. Epub 2004 Jul 28.

DOI:10.1039/b407090a
PMID:15340608
Abstract

CuI/N,N-dimethylglycine-catalyzed coupling reaction of aryl halides with terminal alkynes is carried out in DMF at 100 degrees C to provide the corresponding coupling products in good to excellent yields with a great diversity.

摘要

碘化亚铜/ N，N - 二甲基甘氨酸催化的芳基卤化物与末端炔烃的偶联反应在100℃的N，N - 二甲基甲酰胺中进行，以良好至优异的产率提供了具有丰富多样性的相应偶联产物。

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