通过钛氢化胺化反应得到的α,β-不饱和亚胺以及铑催化的C-H活化官能团化反应
Alpha,beta-unsaturated imines from titanium hydroamination and functionalization by rhodium C-H activation.
作者信息
Cao Changsheng, Li Yahong, Shi Yanhui, Odom Aaron L
机构信息
Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA.
出版信息
Chem Commun (Camb). 2004 Sep 7(17):2002-3. doi: 10.1039/b405620e. Epub 2004 Jul 7.
DOI:10.1039/b405620e
PMID:15340642
Abstract
Titanium pyrrolyl complexes are effective catalysts for the synthesis of alpha,beta-unsaturated imines, which can be further functionalized using Rh-catalyzed alkene or alkyne insertion into the beta-C-H bond.
摘要
吡咯基钛配合物是合成α,β-不饱和亚胺的有效催化剂，这些亚胺可通过铑催化的烯烃或炔烃插入β-C-H键进一步官能化。
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