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一种由通过氢键形成的链衍生而来的一维梯状配位聚合物：链状聚[[水合二吡啶合镍(II)]-μ-2,2'-二硫代二苯甲酸根-κ3O,O':O"]

A one-dimensional ladder-like coordination polymer derived from chains formed via hydrogen bonds: catena-poly[[aquadipyridinenickel(II)]-mu-2,2'-dithiodibenzoato-kappa3O,O':O"].

作者信息

Zhao Wen-Na, Zou Jian-Wei, Yu Qing-Shen

机构信息

Nibo Institute of Technology, Zhejiang University, Ningbo, Zhejiang 315104, People's Republic of China.

出版信息

Acta Crystallogr C. 2004 Sep;60(Pt 9):m443-4. doi: 10.1107/S0108270104017469. Epub 2004 Aug 11.

DOI:10.1107/S0108270104017469
PMID:15345828
Abstract

The title one-dimensional chain nickel(II)-disulfide complex, [Ni(C14H8O4S2)(C5H5N)2(H2O)]n, has each Ni(II) cation coordinated by two N atoms from two pyridine ligands, three carboxylate O atoms from two different dithiodibenzoate ligands and one O atom from a coordinated water molecule, in a distorted octahedral coordination geometry. Each dithiodibenzoate ion links two Ni(II) cations through its carboxylate O atoms, making the structure polymeric. Hydrogen-bond interactions between two shoulder-to-shoulder chains lead to the formation of a ladder-like structure.

摘要

标题为一维链状镍（II）-二硫化物配合物，[Ni(C₁₄H₈O₄S₂)(C₅H₅N)₂(H₂O)]ₙ，每个镍（II）阳离子由来自两个吡啶配体的两个氮原子、来自两个不同二硫代二苯甲酸酯配体的三个羧酸根氧原子以及来自一个配位水分子的一个氧原子配位，形成扭曲的八面体配位几何结构。每个二硫代二苯甲酸酯离子通过其羧酸根氧原子连接两个镍（II）阳离子，使结构成为聚合物。两条肩并肩的链之间的氢键相互作用导致形成梯状结构。

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