Hippelein Martin
Institute of Environmental Medicine, Environmental Toxicology and Hygiene, Brunswiker Strasse 4, 24105 Kiel, Germany.
J Environ Monit. 2004 Sep;6(9):745-52. doi: 10.1039/b401139m. Epub 2004 Aug 18.
During a monitoring campaign concentrations of volatile organic compounds (VOCs) were measured in indoor air of 79 dwellings where occupants had not complained about health problems or unpleasant odour. Parameters monitored were the individual concentration of 68 VOCs and the total concentration of all VOCs inside the room. VOCs adsorbed by Tenax TA were then analysed by means of thermal desorption, gas chromatography and mass spectrometry. The analytical procedure and quantification was done according to the recommendation of the ECA-IAQ Working Group 13 which gave a definition of the total volatile organic compound (TVOC) concentration. Using this recommendation TVOC-concentrations ranged between 33 and 1600 microg m(-3) with a median of 289 microg m(-3). Compounds found in every sample and with the highest concentrations were 2-propanol, alpha-pinene and toluene. Save for a few samples, all concentrations measured have been a factor 2 to 10 lower, compared to data from similar studies. Only a few terpenes and aldehydes were found exceeding published reference data or odour threshold concentrations. However, it has been found that sampling and analysing methods do have a considerable impact on the results, making direct comparisons of studies somewhat questionable. 47% of all samples revealed concentrations exceeding the threshold value of 300 microg TVOC m(-3) set by the German Federal Environmental Agency as a target for indoor air quality. Using the TVOC concentration as defined in the ECA-IAQ methodology is instrumental in assessing exposure to VOCs and identifying sources of VOCs. The background concentrations determined in this study can be used to discuss and interpret target values for individual and total volatile organic compounds in indoor air.
在一次监测活动中,对79户居民室内空气中的挥发性有机化合物(VOCs)浓度进行了测量,这些居民并未抱怨过健康问题或难闻气味。监测的参数包括68种VOCs的个体浓度以及室内所有VOCs的总浓度。然后,通过热脱附、气相色谱和质谱法对吸附在Tenax TA上的VOCs进行分析。分析程序和定量是根据欧洲室内空气质量小组13的建议进行的,该小组给出了总挥发性有机化合物(TVOC)浓度的定义。根据这一建议,TVOC浓度范围在33至1600微克/立方米之间,中位数为289微克/立方米。在每个样品中都发现且浓度最高的化合物是2-丙醇、α-蒎烯和甲苯。除了少数几个样品外,与类似研究的数据相比,所有测量的浓度都低2至10倍。仅发现少数萜类化合物和醛类超过了已公布的参考数据或气味阈值浓度。然而,已经发现采样和分析方法确实对结果有相当大的影响,这使得不同研究之间的直接比较存在一定问题。所有样品中有47%的浓度超过了德国联邦环境局设定的300微克TVOC/立方米的室内空气质量目标阈值。使用欧洲室内空气质量方法中定义的TVOC浓度有助于评估对VOCs的暴露情况并识别VOCs的来源。本研究中确定的背景浓度可用于讨论和解释室内空气中单个和总挥发性有机化合物的目标值。