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润滑性类金刚石生物相容性涂层的摩擦学研究

Tribological study of lubricious DLC biocompatible coatings.

作者信息

Brizuela M, Garcia-Luis A, Viviente J L, Braceras I, Oñate J I

机构信息

Fundación INASMET. Mikeletegi Pasealekua, 2, 20009 San Sebastián, Spain.

出版信息

J Mater Sci Mater Med. 2002 Dec;13(12):1129-33. doi: 10.1023/a:1021129718737.

Abstract

DLC (diamond-like carbon) coatings have remarkable tribological properties due mainly to their good frictional behavior. These coatings can be applied in many industrial and biomedical applications, where sliding can generate wear and frictional forces on the components, such as orthopaedic metal implants. This work reports on the development and tribological characterization of functionally gradient titanium alloyed DLC coatings. A PVD-magnetron sputtering technique has been used as the deposition method. The aim of this work was to study the tribological performance of the DLC coating when metal to metal contact (cobalt chromium or titanium alloys) takes place under dry and lubricated test conditions. Prior work by the authors demonstrates that the DLC coating reduced considerably the wear of the ultra-high-molecular-weight polyethylene (UHMWPE). The DLC coating during mechanical testing exhibited a high elastic recovery (65%) compared to the values obtained from Co-Cr-Mo (15%) and Ti-6Al-4V (23%). The coating exhibited an excellent tribo-performance against the Ti-6Al-4V and Co-Cr-Mo alloys, especially under dry conditions presenting a friction value of 0.12 and almost negligible wear. This coating has passed biocompatibility tests for implant devices on tissue/bone contact according to international standards (ISO 10993).

摘要

类金刚石碳(DLC)涂层具有卓越的摩擦学性能,这主要归因于其良好的摩擦行为。这些涂层可应用于许多工业和生物医学领域,在这些领域中,滑动会在部件上产生磨损和摩擦力,比如骨科金属植入物。本文报道了功能梯度钛合金化DLC涂层的研发及摩擦学特性。采用物理气相沉积磁控溅射技术作为沉积方法。这项工作的目的是研究在干摩擦和润滑测试条件下,当金属与金属(钴铬合金或钛合金)接触时DLC涂层的摩擦学性能。作者之前的工作表明,DLC涂层能显著降低超高分子量聚乙烯(UHMWPE)的磨损。与钴铬钼合金(15%)和Ti-6Al-4V(23%)得到的值相比,DLC涂层在机械测试过程中表现出较高的弹性回复率(65%)。该涂层对Ti-6Al-4V和钴铬钼合金表现出优异的摩擦学性能,特别是在干摩擦条件下,摩擦值为0.12,磨损几乎可以忽略不计。根据国际标准(ISO 10993),该涂层已通过植入装置在组织/骨接触方面的生物相容性测试。

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