Shimizu Makoto, Toyoda Tadahiro
Department of Chemistry for Materials, Mie University, Tsu, Mie 514-8507, Japan.
Org Biomol Chem. 2004 Oct 21;2(20):2891-2. doi: 10.1039/B411127C. Epub 2004 Sep 16.
Titanium tetraiodide promotes an aza-Reformatsky-type reaction of alpha-iodomethyl ketone O-alkyl oximes with carbonyl compounds to give beta-hydroxy ketone O-alkyl oximes in good to high yields.
四碘化钛促进α-碘甲基酮O-烷基肟与羰基化合物发生氮杂Reformatsky型反应,以良好至高的产率生成β-羟基酮O-烷基肟。